Synthesis of Organotin Hydrides by the Hydrogen Exchange Reaction with Silicon Hydrides
نویسندگان
چکیده
منابع مشابه
Silicon hydrides in organic synthesis
In the past few years we have developed an array of composite reducing systems based on combinations of tin or silicon hydrides with various transition-metal homogeneous catalysts such as palladium(O), ruthenium(I1) and molybdenum(0) complexes. These represent a useful family of reducing media that effect highly selective reductions of various organic functional groups, such as allylic heterosu...
متن کاملIntramolecularly Sn–N Coordinated Organotin Hydrides
In recent years, internally Sn–N coordinated organotin hydrides have found an application in organic syntheses, which involve radical chain reactions. Unique reactivity of such hydrides suggests the potential of intramolecular coordination for the control of radical reactions. When the tin hydrides are used in the presence of Lewis acids single-enatiomer outcomes are accessible. This opens a ne...
متن کاملComplex Hydrides for Hydrogen Storage
Complex hydrides, containing a minimum of 7.5 wt% hydrogen, are being investigated as hydrogen storage compounds for automotive use. As a new project, the work to date has largely involved refurbishment of equipment and acquisition of study materials. Initial experiments have confirmed that the instrumentation is functioning and that the data being obtained agree with that in the literature. In...
متن کاملHydrogen storage in complex metal hydrides
Complex metal hydrides such as sodium aluminohydride (NaAlH4) and sodium borohydride (NaBH4) are solid-state hydrogen-storage materials with high hydrogen capacities. They can be used in combination with fuel cells as a hydrogen source thus enabling longer operation times compared with classical metal hydrides. The most important point for a wide application of these materials is the reversibil...
متن کاملProduction of hydrogen from chemical hydrides via hydrolysis with steam
This is an investigation of a gas/solid chemical reaction between steam and chemical hydrides that liberates pure hydrogen gas. The aim is to obtain fundamental kinetic, chemical, and thermodynamic data on the reaction so that sufficient information is known to evaluate this technology rigorously for its potential as a means of delivering hydrogen for fuel cells and internal combustion engines....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1967
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.70.82